By Robert L. Thorp, Virginia Bower
Spirit and formality: The Morse selection of historic chinese language paintings, by way of Thorp, Robert L. and Virginia Bower
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Spirit and formality: The Morse selection of old chinese language paintings, through Thorp, Robert L. and Virginia Bower
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Extra resources for Spirit and Ritual Morse Collect
1. 2. g. by the (n, γ) reaction with slow neutrons in a nuclear reactor. During the irradiation a great number of other radioisotopes are also formed. From this mixture it is necessary to isolate only radioisotopes of the metal to be determined and in a radiochemically pure form. e. miUigram amounts of the element to be separated) is ANALYTICAL APPLICATIONS 47 added and many separation steps are carried out by which the desked metal is isolated in a radiochemically pure form. The separation steps need not to be quantitative as the total activity of the element to be determined which was induced by the irradiation can be calculated from the relation: A = A*XIM (90) where ^4* is the activity of the recovered fraction of the weight M, and Ζ the amount of carrier added.
INFLUENCE OF T H E S T A B I L I T Y OF M E T A L CHELATES From eq. (72) it can be seen that the higher the stability constant of the metal chelates MA^, the higher also is the extraction constant and the extraction can be carried out from more acidic solutions. THEORY OF THE SOLVENT EXTRACTION OF METAL CHELATES 35 For instance, the stabihty of metal acetylacetonates decreases in the foUowing order (B 62, Y 6): paUadium, iron (III), berylhum, copper (II), indium and scandium, aluminium, uranium (VI), thorium, nickel, cobalt, zinc, lanthanum, manganese, and magnesium.
Theory of substoicheiometric determinations From the theory of substoicheiometric determinations given by Ruziöka and Stary (R31, R35), conditions can be calculated at which the organic reagent reacts quantitatively with the excess of the metal ion to give an extractable chelate MA^. e. [MA^lorgKorg > 0-999 (84) CHA^org/Λ^ where CHA denotes the total concentration of the reagent and Vorg is the volume of the organic phase. This condition guarantees the isolation of the same amount of metal with a precision of better than 0-1 per cent.